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Project

Cationic gold-catalyzed cyclizations for the preparation of complex azaheterocycles

Outputs and Outcomes

Code

3E004915

Duration

01 October 2015 → 31 December 2016

Funding

Research Foundation - Flanders (FWO)

Promotor

Christian Stevens

Fellow

Wouter Debrouwer

Research disciplines

Natural sciences
- Inorganic chemistry
- Organic chemistry

Keywords

catalysis homogeneous gold azaheterocyclic vinylidene enyne cyclization ligands

Project description

Cationic homogeneous Au(I)-catalysts will be evaluated for the synthesis of complex N-containing cyclic compounds. Firstly, both intra- and intermolecular 1,n-enyne cyclizations will be studied, where the attack of a N-nucleophile is crucial. Secondly, the reaction between in situ formed Au-vinylidenes and N-nucleophiles will be investigated.

English

Dutch

English

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