Project

Excited molecules: development of photo- and redox-pathways as tools for green chemistry and bio-resource valorization

Code
BOF/STA/202102/003
Duration
10 March 2021 → 09 March 2025
Funding
Regional and community funding: Special Research Fund
Research disciplines
  • Natural sciences
    • Organic chemical synthesis
    • Flow chemistry
    • Organic green chemistry
    • Photochemistry
Keywords
photochemistry single electron transfer renewable resources
 
Project description

The research program proposed herein will focus on the study of alternative energy input processes for chemical synthesis, including direct light-induced chemical derivatization, the closely related photo-redox processes and electrochemistry. Leveraged by micro-reactor technology, these alternate mechanistic pathways are evolving into valuable and green chemistry tools. The economic viability of both photo- and electro-chemically induced singe electron transfer (SET) redox reactions and of singlet/triplet chemistry is highly increased in a microfluidic set-up and can culminate in the direct or indirect use of solar light to obtain high added value chemicals. In addition, the distinct character of these mechanisms grant them a good compatibility with the highly functionalised nature of natural resources.The investigation of these alternative energy input processes for chemical synthesis thus represents a link between synthetic organic chemistry, the development of new reactor systems and bioresource valorization.