Research Explorer

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Researcher

Catherine Cazin

Awards & Distinctions

183 Results

2025

Synthesis of gold(I) and palladium(II) complexes bearing N-heterocyclic carbene thioglucosides with selective cytotoxicity towards ovarian cancer cells

Francis BruMaxime VanwynsbergheEleonora BotterGiovanni TononFabiano VisentinAlessia SchiavoFlavio RizzolioCatherine CazinThomas Scattolin

A1 Journal Article in EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

[Cu(NHC)(OR)] (R = C(CF<sub>3</sub>)<sub>3</sub>) complexes for N-H and S-H bond activation and as pre-catalysts in the Chan-Evans-Lam reaction

Tommaso RuggieroKristof Van HeckeCatherine CazinSteven Nolan

U Journal Article in DALTON TRANSACTIONS

2024

A simply accessible organometallic system to gauge electronic properties of N-heterocyclic carbenes

Francis BruRex S. C. CharmanLaurens BourdaKristof Van HeckeLaurence GrimaudDavid J. LiptrotCatherine Cazin

A1 Journal Article in DALTON TRANSACTIONS

Continuous flow synthesis of group 11 metal-NHC complexes [M(IPr)(OC(H)(CF3)2)] (with M=Cu, Ag and Au)

Andreas SimoensGianluca CariSylwia OstrowskaCatherine CazinChristian StevensSteven Nolan

A1 Journal Article in ASIAN JOURNAL OF ORGANIC CHEMISTRY

Machine learning directed discovery and optimisation of a platinum-catalysed amide reduction

Eleonora CasilloBenon MaliszewskiCésar Alejandro Urbina BlancoThomas ScattolinCatherine CazinSteven Nolan

U Journal Article in CHEMICAL COMMUNICATIONS

Platinum(II)-N-heterocyclic carbene and thioether complexes and their application in hydrosilylation of alkenes and alkynes

Benon MaliszewskiSteven NolanCatherine CazinFady Nahra

The role of the stabilizing/leaving group in palladium catalysed cross-coupling reactions

Lorenzo PalioFrancis BruTommaso RuggieroLaurens BourdaKristof Van HeckeCatherine CazinSteven Nolan

A1 Journal Article in DALTON TRANSACTIONS

2023

Advances in the synthesis and applications of N-heterocyclic carbene metal complexes with a focus on the weak base route

Thomas ScattolinAleksei LogvinovNikolaos TzourasCatherine CazinSteven Nolan

A1 Journal Article in ORGANOMETALLICS

An air-stable [Cu(NHC)(OR)] (R = C(H)(CF3)2) complex for C-H, N-H and S-H bond activation

Sylwia OstrowskaPierre ArnautDavid J. LiptrotCatherine CazinSteven Nolan

A1 Journal Article in CHEMICAL COMMUNICATIONS

Correlation of experimental and calculated reaction enthalpies with ligand donor strengths

Julian LöfflerSofie Vanden BroeckCatherine CazinSteven NolanViktoria H. Gessner

A1 Journal Article in CHEMISTRY-A EUROPEAN JOURNAL

Deep red to near-infrared light-controlled ruthenium-catalyzed olefin metathesis

David C. CabaneroJennifer A. NguyenCatherine CazinSteven NolanTomislav Rovis

A1 Journal Article in ACS CATALYSIS

Gold complexes with remote-substituted amino N-heterocyclic carbenes

Sofie Vanden BroeckNikolaos TzourasMarina SaabKristof Van HeckeBusra DereliIda RitaccoLuigi CavalloGeorgios C. C. VougioukalakisPierre BraunsteinSteven Nolan et al.

A1 Journal Article in DALTON TRANSACTIONS

Homogeneously catalysed functionalization of methane

Sofie Vanden BroeckCatherine CazinSteven Nolan

Bookchapter in Methane conversion routes : status and prospects

Learning green chemistry principles by comparing three synthetic routes to a copper-NHC (NHC = N-heterocyclic carbene) complex

Francis BruSofie Vanden BroeckGianmarco PisanòKlaartje De BuysserCatherine Cazin

A1 Journal Article in JOURNAL OF CHEMICAL EDUCATION

Mechanistic insights into the synthesis of [Rh(acac)(CO)(NHC)] (NHC=N-heterocyclic carbene) complexes using a weak base

Sébastien GuilletIbni Hashim ishfaqMarek BelišKristof Van HeckeCatherine CazinSteven Nolan

A1 Journal Article in EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

NMR characterization and antimicrobial activity of mechanically synthesized organometallic complexes

Lama HamdounaOlivier LafonCatherine Cazin

Novel Au(I) and Pd(II) phosphine and NHC complexes : unveiling their potential in homogeneous catalysis

Vladislav VoloshkinSteven NolanCatherine Cazin

Palladium- and ruthenium-based catalytic systems by N-heterocyclic carbene as ancillary ligands for cross-coupling and ring-closing metathesis (RCM) reactions

Yaxu LiuCatherine CazinKristof Van Hecke

PtII-N‐heterocyclic carbene complexes in solvent‐free alkene hydrosilylation

Benon MaliszewskiTahani Al Chami Al BayrakdarPerrine LambertLama HamdounaXavier TrivelliLuigi CavalloAlbert PoaterMarek BelišOlivier LafonKristof Van Hecke et al.

A1 Journal Article in CHEMISTRY-A EUROPEAN JOURNAL

Simply accessible platinum(II) complexes enabling alkene hydrosilylation at ppm catalyst loadings

Benon MaliszewskiEleonora CasilloPerrine LambertFady NahraCatherine CazinSteven Nolan

A1 Journal Article in CHEMICAL COMMUNICATIONS

Straightforward synthesis of Au-NHC complexes : streamlined routes and pioneering photocatalytic applications

Ekaterina MartynovaSteven NolanCatherine Cazin

Suzuki-Miyaura cross-coupling of amides by N-C cleavage mediated by air-stable, well-defined [Pd(NHC)(sulfide)Cl2] catalysts : reaction development, scope, and mechanism

Shiyi YangXiang YuYaxu LiuMichele TomasiniLucia CaporasoAlbert PoaterLuigi CavalloCatherine CazinSteven NolanMichal Szostak

A1 Journal Article in JOURNAL OF ORGANIC CHEMISTRY

Synthesis of transition metal complexes under solvent-free conditions

Gianmarco PisanoCatherine CazinKristof Van Hecke

Synthesis, characterization, and reactivity of [Pd(phosphine)(py)Cl2] (PEPPSI) and [Pd(phosphine)Cl2]2 complexes

Vladislav VoloshkinYaxu LiuMarek BelišMin PengKristof Van HeckeCatherine CazinSteven Nolan

A1 Journal Article in DALTON TRANSACTIONS

Towards greener and milder ways to prepare and use transition metal NHC complexes in catalysis

Sébastien GuilletSteven NolanCatherine Cazin

2022

A green route to platinum N-heterocyclic carbene complexes : mechanism and expanded scope

Benon MaliszewskiIda RitaccoMarek BelišIbni Hashim ishfaqNikolaos TzourasLucia CaporasoLuigi CavalloKristof Van HeckeFady NahraCatherine Cazin et al.

A1 Journal Article in DALTON TRANSACTIONS

A green synthesis of carbene-metal-amides (CMAs) and carboline-derived CMAs with potent in vitro and ex vivo anticancer activity

Nikolaos TzourasThomas ScattolinAlberto GobboSubhrajyoti BhandaryFlavio RizzolioEnrico CavarzeraniVincenzo CanzonieriKristof Van HeckeGeorgios C. VougioukalakisCatherine Cazin et al.

A1 Journal Article in CHEMMEDCHEM

A simple synthetic route to well-defined [Pd(NHC)Cl(1-tBu-indenyl)] pre-catalysts for cross-coupling reactions

Yaxu LiuThomas ScattolinAlberto GobboMarek BelišKristof Van HeckeSteven NolanCatherine Cazin

A1 Journal Article in EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A versatile palladium synthon : [Pd(NHC)(PhC equivalent to CPh)]

Francis Brumathieu lesieurAlbert PoaterAlexandra SlawinLuigi CavalloCatherine Cazin

A1 Journal Article in CHEMISTRY-A EUROPEAN JOURNAL

Buchwald-Hartwig amination and C-S/S-H metathesis of aryl sulfides by selective C-S cleavage mediated by air- and moisture- stable [Pd(NHC)(mu-Cl)Cl]2 precatalysts : unified mechanism for activation of inert C-S bonds

Shiyi YangXiang YuAlbert PoaterLuigi CavalloCatherine CazinSteven NolanMichal Szostak

A1 Journal Article in ORGANIC LETTERS

Buchwald-Hartwig amination and C-S/S-H metathesis of aryl sulfides by selective C-S cleavage mediated by air- and moisture- stable [Pd(NHC)(μ-Cl)Cl]2 precatalysts : unified mechanism for activation of inert C-S bonds

Shiyi YangXiang YuAlbert PoaterLuigi CavalloCatherine CazinSteven NolanMichal Szostak

A1 Journal Article in ORGANIC LETTERS

Continuous flow synthesis of NHC‐coinage metal amido and thiolato complexes : a mechanism‐based process development

Thibault CauwenberghNikolaos TzourasThomas ScattolinAndreas SimoensChristian StevensCatherine CazinSteven Nolan

A2 Journal Article in CHEMISTRY-METHODS

Continuous flow synthesis of metal-NHC complexes

Andreas SimoensThomas ScattolinThibault CauwenberghGianmarco PisanoCatherine CazinSteven NolanChristian Stevens

Energy transfer (EnT) photocatalysis enabled by gold-N-heterocyclic carbene (NHC) complexes

Ekaterina MartynovaVladislav VoloshkinSébastien GuilletFrancis BruMarek BelišKristof Van HeckeCatherine CazinSteven Nolan

A1 Journal Article in CHEMICAL SCIENCE

Improved synthetic routes to N-heterocyclic carbene-metal-diketonato complexes of gold and copper

Ibni Hashim ishfaqNikolaos TzourasXinyuan MaLaurens BourdaKristof Van HeckeSteven NolanCatherine Cazin

A1 Journal Article in DALTON TRANSACTIONS

NHC complexes in flow (NHC = N‐heterocyclic carbene)

Andreas SimoensThomas ScattolinThibault CauwenberghNikolaos TzourasGianmarco PisanòCatherine CazinSteven NolanChristian Stevens

Novel gold(I) complexes for catalysis : synthesis, characterization and applications

Sofie Vanden BroeckCatherine CazinKristof Van Hecke

Synthesis of carbene-metal-amido (CMA) complexes and their use as precatalysts for the activator-free, gold-catalyzed addition of carboxylic acids to alkynes

Ibni Hashim ishfaqNikolaos TzourasWim JanssensThomas ScattolinLaurens BourdaSubhrajyoti BhandaryKristof Van HeckeSteven NolanCatherine Cazin

A1 Journal Article in CHEMISTRY-A EUROPEAN JOURNAL

Synthetic access to aromatic alpha-haloketones

Marre PorréGianmarco PisanoFady NahraCatherine Cazin

A1 Journal Article in MOLECULES

The effect of cocoa alkalization on the non-volatile and volatile mood-enhancing compounds

Eleni SiorikiEmmy TuenterDavy Van de WalleValérie LemarcqCatherine CazinSteven NolanLuc PietersKoen Dewettinck

A1 Journal Article in FOOD CHEMISTRY

Versatile and highly efficient trans-[Pd(NHC)Cl2(DMS/THT)] precatalysts for C−N and C−C coupling reactions in green solvents

Yaxu LiuVladislav VoloshkinThomas ScattolinMin PengKristof Van HeckeSteven NolanCatherine Cazin

A1 Journal Article in EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Well-defined N-heterocyclic carbene coinage metal complexes : synthesis, characterisation, and catalytic applications in alkyne transformations

Ibni Hashim ishfaqCatherine CazinKristof Van Hecke

2021

A simple synthetic route to [Rh(acac)(CO)(NHC)] complexes : ligand property diagnostic tools and precatalysts

Sébastien GuilletGianmarco PisanòSoumyadeep ChakraborttyBernd H. MuellerJohannes G. de VriesPaul C. J. KamerCatherine CazinSteven Nolan

A1 Journal Article in EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

An alkene dance

Catherine Cazin

Editorial material

Au...H-C hydrogen bonds as design principle in gold(I) catalysis

Heidar DarmandehJulian LoefflerNikolaos TzourasBüsra DereliThorsten ScherpfKai-Stephan FeichtnerSofie Vanden BroeckKristof Van HeckeMarina SaabCatherine Cazin et al.

A1 Journal Article in ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Continuous flow synthesis of metal-NHC complexes

Andreas SimoensThomas ScattolinThibault CauwenberghGianmarco PisanòCatherine CazinChristian StevensSteven Nolan

A1 Journal Article in CHEMISTRY-A EUROPEAN JOURNAL

Conversion of Pd(i) off-cycle species into highly efficient cross-coupling catalysts

Yaxu LiuVladislav VoloshkinThomas ScattolinLuigi CavalloBusra DereliCatherine CazinSteven Nolan

A1 Journal Article in DALTON TRANSACTIONS

General mechanochemical synthetic protocol to late transition metal-NHC (N-Heterocyclic Carbene) complexes

Gianmarco PisanòCatherine Cazin

A1 Journal Article in ACS SUSTAINABLE CHEMISTRY & ENGINEERING

Impact of alkalization conditions on the phytochemical content of cocoa powder and the aroma of cocoa drinks

Eleni SiorikiValérie LemarcqFauzan AlhakimHarry TriharyogiEmmy TuenterCatherine CazinSteven NolanLuc PietersDavy Van de WalleKoen Dewettinck

A1 Journal Article in LWT-FOOD SCIENCE AND TECHNOLOGY

Manganese-N-heterocyclic carbene (NHC) complexes : an overview

Sofie Vanden BroeckCatherine Cazin

A1 Journal Article in POLYHEDRON

Simple synthesis of [Ru(CO3)(NHC)(p-cymene)] complexes and their use in transfer hydrogenation catalysis

Xinyuan MaSébastien GuilletYaxu LiuCatherine CazinSteven Nolan

A1 Journal Article in DALTON TRANSACTIONS

Simple synthetic routes to carbene-M-amido (M=Cu, Ag, Au) complexes for luminescence and photocatalysis applications

Nikolaos TzourasEkaterina MartynovaXinyuan MaThomas ScattolinBenjamin HuppHendrik BusenMarina SaabZiyun ZhangLaura FaliveneGianmarco Pisanò et al.

A1 Journal Article in CHEMISTRY-A EUROPEAN JOURNAL

Straightforward synthesis of [Cu(NHC)(alkynyl)] and [Cu(NHC)(thiolato)] complexes (NHC = N-heterocyclic carbene)

Ibni Hashim ishfaqThomas ScattolinNikolaos TzourasLaurens BourdaKristof Van HeckeIda RitaccoLucia CaporasoLuigi CavalloSteven NolanCatherine Cazin

A1 Journal Article in DALTON TRANSACTIONS

Sustainability in Ru- and Pd-based catalytic systems using N-heterocyclic carbenes as ligands

Fady NahraCatherine Cazin

A1 Journal Article in CHEMICAL SOCIETY REVIEWS

Synthesis and catalytic activity of palladium complexes bearing N-heterocyclic carbenes (NHCs) and 1,4,7-triaza-9-phosphatricyclo[5.3.2.1]tridecane (CAP) ligands

Thomas ScattolinVladislav VoloshkinEkaterina MartynovaSofie Vanden BroeckMarek BelišCatherine CazinSteven Nolan

A1 Journal Article in DALTON TRANSACTIONS

Synthesis of gold(I)-trifluoromethyl complexes and their role in generating spectroscopic evidence for a gold(I)-difluorocarbene species

Sofie Vanden BroeckDavid J. NelsonAlba ColladoLaura FaliveneLuigi CavalloDavid B. CordesAlexandra M. Z. SlawinKristof Van HeckeFady NahraCatherine Cazin et al.

A1 Journal Article in CHEMISTRY-A EUROPEAN JOURNAL

Synthetic access to ring-expanded N-Heterocyclic Carbene (RE-NHC) copper complexes and their performance in click chemistry

Jonathan W. HallDamien BouchetMary F. MahonMichael K. WhittleseyCatherine Cazin

A1 Journal Article in ORGANOMETALLICS

The 'weak base route' leading to transition metal-N-heterocyclic carbene complexes

Ekaterina MartynovaNikolaos TzourasGianmarco PisanoCatherine CazinSteven Nolan

A1 Journal Article in CHEMICAL COMMUNICATIONS

2020

A mechanistically and operationally simple route to metal–N‐heterocyclic carbene (NHC) complexes

Nikolaos TzourasFady NahraLaura FaliveneLuigi CavalloMarina SaabKristof Van HeckeAlba ColladoChristopher J. CollettAndrew D. SmithCatherine Cazin et al.

A1 Journal Article in CHEMISTRY-A EUROPEAN JOURNAL

Aerobic synthesis of N-sulfonylamidines mediated by N-heterocyclic carbene copper(I) catalysts

Falima LazregMarie VasseurAlexandra M. Z. SlawinCatherine Cazin

A1 Journal Article in BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY

Au(I)-catalyzed hydration of 1-Iodoalkynes leading to alpha-Iodoketones

Alberto Gomez-HerreraIbni Hashim ishfaqMarre PorréFady NahraCatherine Cazin

A1 Journal Article in EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Mechanochemical synthesis of Cu(i)-N-heterocyclic carbene complexes

Gianmarco PisanoCatherine Cazin

A1 Journal Article in GREEN CHEMISTRY

[Pd(NHC)(mu-Cl)Cl](2) : versatile and highly reactive complexes for cross-coupling reactions that avoid formation of inactive Pd(I) off-cycle products

Tongliang ZhouSiyue MaFady NahraAlan M. C. ObledAlbert PoaterLuigi CavalloCatherine CazinSteven NolanMichal Szostak

A1 Journal Article in ISCIENCE

2019

Bulky-yet-flexible carbene ligands and their use in palladium cross-coupling

Sofie Vanden BroeckFady NahraCatherine Cazin

A1 Journal Article in INORGANICS

Cu–NHC azide complex : synthesis and reactivity

Michael TroseFady NahraDavid B CordesAlexandra MZ SlawinCatherine Cazin

A1 Journal Article in CHEMICAL COMMUNICATIONS

Electronic effects in mixed N-heterocyclic carbene/phosphite indenylidene ruthenium metathesis catalysts

Yannick D. BidalCésar A. Urbina-BlancoAlbert PoaterDavid B. CordesAlexandra M. Z. SlawinLuigi CavalloCatherine Cazin

A1 Journal Article in DALTON TRANSACTIONS

Gold(I) catalysed regio- and stereoselective intermolecular hydroamination of internal alkynes : towards functionalised azoles

Christophe MichonJoachim GilbertXavier TrivelliFady NahraCatherine CazinFrancine Agbossou-NiedercornSteven Nolan

A1 Journal Article in ORGANIC & BIOMOLECULAR CHEMISTRY

Mizoroki-Heck cross-coupling of acrylate derivatives with aryl halides catalyzed by palladate pre-catalysts

Mohammad Shahidul IslamFady NahraNikolaos TzourasAssem BarakatCatherine CazinSteven NolanAbdullah Mohammed Al-Majid

A1 Journal Article in EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Palladate precatalysts for the formation of C-N and C-C bonds

Caroline M ZinserKatie G WarrenFady NahraAbdullah Al-MajidAssem BarakatMohammad Shahidul IslamSteven NolanCatherine Cazin

A1 Journal Article in ORGANOMETALLICS

Synthesis and reactivity of [Au(NHC)(Bpin)] complexes

Caroline M ZinserFady NahraLaura FaliveneMarcel BrillDavid B CordesAlexandra MZ SlawinLuigi CavalloCatherine CazinSteven Nolan

A1 Journal Article in CHEMICAL COMMUNICATIONS

Synthesis of di-substituted alkynes via palladium-catalyzed decarboxylative coupling and C-H activation

Alberto Gómez-HerreraFady NahraJiufeng WuFrédéric IzquierdoMarcel BrillCatherine CazinSteven Nolan

A1 Journal Article in CHEMISTRYSELECT

2018

Copper(I)-N-heterocyclic carbene complexes as efficient catalysts for the synthesis of 1,4-disubstituted 1,2,3-sulfonyltriazoles in air

Faïma LazregCatherine Cazin

A1 Journal Article in ORGANOMETALLICS

Dinuclear N-heterocyclic carbene copper(I) complexes

Michael TroseFady NahraCatherine Cazin

A1 Journal Article in COORDINATION CHEMISTRY REVIEWS

Grignard reagents and palladium

David J. NelsonCatherine CazinSteven Nolan

A1 Journal Article in PHYSICAL SCIENCES REVIEWS

Historic perspectives on carbenes

Fady NahraCatherine Cazin

Bookchapter in N-Heterocyclic carbenes in catalytic organic synthesis

Hydrogenation of carbon dioxide

Catherine CazinFady Nahra

Bookchapter in Science of synthesis : catalytic reduction in organic synthesis 1

Insights into the catalytic activity of [Pd(NHC)(cin)Cl] (NHC=IPr, IPrCl, IPrBr) complexes in the Suzuki-Miyaura reaction

Frédéric IzquierdoCaroline ZinserYury MinenkovDavid B CordesAlexandra MZ SlawinLuigi CavalloFady NahraCatherine CazinSteven Nolan

A1 Journal Article in CHEMCATCHEM

Ligand-directed reactivity in dioxygen and water binding to cis-[Pd(NHC)2(η2-O2)]

Taryn D PalluccioXiaochen CaiSubhojit MajumdarLeonardo F SerafimNeil C TomsonKarl WieghardtCatherine CazinSteven NolanElena V Rybak-AkimovaMiguel Ángel Fernández-González et al.

A1 Journal Article in JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The role of the metal in the dual-metal catalysed hydrophenoxylation of diphenylacetylene

Oscar F González-BelmanJ Oscar C Jiménez-HallaFady NahraCatherine CazinAlbert Poater

A1 Journal Article in CATALYSIS SCIENCE & TECHNOLOGY

Towards environmentally friendlier Suzuki-Miyaura reactions with precursors of Pd-NHC (NHC = N-heterocyclic carbene) complexes

Caroline M ZinserKatie G WarrenRebecca E MeadowsFady NahraAbdullah M Al-MajidAssem BarakatMohammad S IslamSteven NolanCatherine Cazin

A1 Journal Article in GREEN CHEMISTRY

2017

A simple synthetic entryway into palladium cross-coupling catalysis

Caroline M ZinserFady NahraMarcel BrillRebecca E MeadowsDavid B CordesAlexandra MZ SlawinSteven NolanCatherine Cazin

A1 Journal Article in CHEMICAL COMMUNICATIONS

Copper(I)-NHC complexes as NHC transfer agents

Fady NahraAlberto Gomez-HerreraCatherine Cazin

A1 Journal Article in DALTON TRANSACTIONS

Expedient syntheses of neutral and cationic Au(I)-NHC complexes

Richard M. P. VeenboerDanila GasperiniFady NahraDavid B CordesAlexandra MZ SlawinCatherine CazinSteven Nolan

A1 Journal Article in ORGANOMETALLICS

Hydrophenoxylation of internal alkynes catalysed with a heterobimetallic Cu-NHC/Au-NHC system

Faima LazregStefano GuidoneAlberto Gomez-HerreraFady NahraCatherine Cazin

A1 Journal Article in DALTON TRANSACTIONS

Inner-sphere versus outer-sphere coordination of BF4- in a NHC-gold(I) complex

Richard MP VeenboerAlba ColladoStéphanie DupuyTomas LeblLaura FaliveneLuigi CavalloDavid B CordesAlexandra MZ SlawinCatherine CazinSteven Nolan

A1 Journal Article in ORGANOMETALLICS

Investigating the structure and reactivity of azolyl-based copper(I)-NHC complexes : the role of the anionic ligand

Michael TroseFady NahraAlbert PoaterDavid B. CordesAlexandra M. Z. SlawinLuigi CavalloCatherine Cazin

A1 Journal Article in ACS CATALYSIS

N-Heterocyclic carbenes in catalytic organic synthesis, vol. 1

N-Heterocyclic carbenes in catalytic organic synthesis, vol. 2

N-Heterocyclic carbenes in catalytic organic synthesis, workbench edition

N-heterocyclic carbene complexes of palladium in oxygen atom transfer reactions involving the making and breaking of N-O bonds

Xiaochen CaiSubhojit MajumdarLeonardo F SerafimManuel TempradoSteven NolanCatherine CazinBurjor CaptainCarl D Hoff

A1 Journal Article in INORGANICA CHIMICA ACTA

Neutral dinuclear copper(I)-NHC complexes : synthesis and application in the hydrosilylation of ketones

Michael TroseFaima LazregTao ChangFady NahraDavid B CordesAlexandra MZ SlawinCatherine Cazin

A1 Journal Article in ACS CATALYSIS

2016

Generalization of the copper to late-transition-metal transmetallation to carbenes beyond N-heterocyclic carbenes

Yannick D BidalOrlando SantoroMohand MelaimiDavid B CordesAlexandra MZ SlawinGuy BertrandCatherine Cazin

A1 Journal Article in CHEMISTRY-A EUROPEAN JOURNAL

Grignard reagents and palladium

David J NelsonCatherine CazinSteven Nolan

Bookchapter in Grignard reagents and transition metal catalysts : formation of C-C bonds by cross-coupling

Homoleptic and heteroleptic bis-NHC Cu(I) complexes as carbene transfer reagents

Orlando SantoroFaima LazregDavid B CordesAlexandra MZ SlawinCatherine Cazin

A1 Journal Article in DALTON TRANSACTIONS

Light-stable silver N-heterocyclic carbene catalysts for the alkynylation of ketones in air

Faima LazregMathieu LesieurAndrew J SamsonCatherine Cazin

A1 Journal Article in CHEMCATCHEM

Sequential functionalization of alkynes and alkenes catalyzed by gold(I) and palladium(II) N-heterocyclic carbene complexes

Alberto Gomez-HerreraFady NahraMarcel BrillSteven NolanCatherine Cazin

A1 Journal Article in CHEMCATCHEM

Synthesis, characterization and catalytic activity of stable [(NHC)H][ZnXY2] (NHC = N-heterocyclic carbene, X, Y = Cl, Br) species

Orlando SantoroFady NahraDavid B CordesAlexandra MZ SlawinSteven NolanCatherine Cazin

A1 Journal Article in JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Transition metal bifluorides

Fady NahraMarcel BrillAlberto Gomez-HerreraCatherine CazinSteven Nolan

A1 Journal Article in COORDINATION CHEMISTRY REVIEWS

Transition metal-catalyzed carboxylation of organic substrates with carbon dioxide

Marcel BrillFaima LazregCatherine CazinSteven Nolan

A1 Journal Article in Topics in Organometallic Chemistry

2015

A simple access to transition metal cyclopropenylidene complexes

Yannick D BidalMathieu LesieurMohand MelaimiDavid B CordesAlexandra MZ SlawinGuy BertrandCatherine Cazin

A1 Journal Article in CHEMICAL COMMUNICATIONS

A straightforward metal-free synthesis of 2-substituted thiazolines in air

Michael TroseFaima LazregMathieu LesieurCatherine Cazin

A1 Journal Article in GREEN CHEMISTRY

Conducting olefin metathesis reactions in air : breaking the paradigm

Stefano GuidoneOlivier SongisFady NahraCatherine Cazin

A1 Journal Article in ACS CATALYSIS

Copper N-heterocyclic carbene complexes as active catalysts for the synthesis of 2-substituted oxazolines from nitriles and aminoalcohols

Michael TroseFaima LazregMathieu LesieurCatherine Cazin

A1 Journal Article in JOURNAL OF ORGANIC CHEMISTRY

Copper(I) complexes bearing carbenes beyond classical N-heterocyclic carbenes : synthesis and catalytic activity in 'click chemistry'

Yannick D BidalMathieu LesieurMohand MelaimiFady NahraDavid B CordesKasun S Athukorala ArachchigeAlexandra MZ SlawinGuy BertrandCatherine Cazin

A1 Journal Article in ADVANCED SYNTHESIS & CATALYSIS

Copper-NHC complexes in catalysis

Faima LazregFady NahraCatherine Cazin

A1 Journal Article in COORDINATION CHEMISTRY REVIEWS

N-heterocyclic carbene copper(I) catalysed N-methylation of amines using CO2

Orlando SantoroFaima LazregYury MinenkovLuigi CavalloCatherine Cazin

A1 Journal Article in DALTON TRANSACTIONS

Palladium(0) NHC complexes : a new avenue to highly efficient phosphorescence

Adam F HenwoodMathieu LesieurAshu K BansalVincent LemaurDavid BeljonneDavid G ThompsonDuncan GrahamAlexandra MZ SlawinIfor DW SamuelCatherine Cazin et al.

A1 Journal Article in CHEMICAL SCIENCE

Phosphite ligands in Ru-based olefin metathesis catalysts

Xavier BantreilCatherine Cazin

A1 Journal Article in MONATSHEFTE FUR CHEMIE

Ruthenium indenylidene '1st generation' olefin metathesis catalysts containing triisopropyl phosphite

Stefano GuidoneFady NahraAlexandra MZ SlawinCatherine Cazin

A1 Journal Article in BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY

Ruthenium olefin metathesis catalysts containing fluoride

Stefano GuidoneOlivier SongisLaura FaliveneFady NahraAlexandra MZ SlawinHeiko JacobsenLuigi CavalloCatherine Cazin

A1 Journal Article in ACS CATALYSIS

Selective NaOH-catalysed hydration of aromatic nitriles to amides

Thibault E SchmidAlberto Gomez-HerreraOlivier SongisDeborah SneddonAntoine RevolteFady NahraCatherine Cazin

A1 Journal Article in CATALYSIS SCIENCE & TECHNOLOGY

Synthesis of homoleptic and heteroleptic bis-N-heterocylic carbene group 11 complexes

Faima LazregDavid B CordesAlexandra MZ SlawinCatherine Cazin

A1 Journal Article in ORGANOMETALLICS

Versatile relay and cooperative palladium(0) N-heterocyclic carbene/copper(I) N-heterocyclic carbene catalysis for the synthesis of tri- and tetrasubstituted alkenes

Mathieu LesieurYannick D BidalFaima LazregFady NahraCatherine Cazin

A1 Journal Article in CHEMCATCHEM

2014

A cooperative Pd-Cu system for direct C-H bond arylation

Mathieu LesieurFaima LazregCatherine Cazin

A1 Journal Article in CHEMICAL COMMUNICATIONS

Copper-catalyzed regioselective formation of tri- and tetrasubstituted vinylboronates in air

Yannick D BidalFaima LazregCatherine Cazin

A1 Journal Article in ACS CATALYSIS

Enthalpies of ligand substitution for [Mo(eta(C5H5)-C-5)(CO)(2)(NO)] : the role of pi-bonding effects in metal-ligand bond strengths

Subhojit MajumdarBurjor CaptainCatherine CazinSteven NolanCarl D Hoff

A1 Journal Article in JOURNAL OF CHEMICAL THERMODYNAMICS

Medical applications of NHC-gold and -copper complexes

Faima LazregCatherine Cazin

Bookchapter in N-Heterocyclic carbenes : effective tools for organometallic synthesis

NHC-copper complexes and their applications

Faima LazregCatherine Cazin

Bookchapter in N-Heterocyclic carbenes : effective tools for organometallic synthesis

Ruthenium-indenylidene and other alkylidene containing olefin metathesis catalysts

César A. Urbina-BlancoStefano GuidoneSteven NolanCatherine Cazin

Bookchapter in Olefin metathesis : theory and practice

Selective ethenolysis and oestrogenicity of compounds from cashew nut shell liquid

Jennifer JulisStuart A BartlettSabrina BaaderNicola BeresfordEdwin J RoutledgeCatherine CazinDavid J Cole-Hamilton

A1 Journal Article in GREEN CHEMISTRY

Two commercially available initiators for the retarded ring-opening metathesis polymerization of dicyclopentadiene

Anita LeitgebJulia WappelCésar A. Urbina-BlancoSimone StrasserChristina WapplCatherine CazinChristian. Slugovc

A1 Journal Article in MONATSHEFTE FUR CHEMIE

[Pd(mu-Cl)Cl(IPr*)](2) : a highly hindered pre-catalyst for the synthesis of tetra-ortho-substituted biaryls via Grignard reagent cross-coupling

Mathieu LesieurAlexandra MZ SlawinCatherine Cazin

A1 Journal Article in ORGANIC & BIOMOLECULAR CHEMISTRY

2013

A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes

Orlando SantoroAlba ColladoAlexandra MZ SlawinSteven NolanCatherine Cazin

A1 Journal Article in CHEMICAL COMMUNICATIONS

Copper N-heterocyclic carbene complexes in catalysis

Jonathan D EgbertCatherine CazinSteven Nolan

A1 Journal Article in CATALYSIS SCIENCE & TECHNOLOGY

Energetics of the ruthenium-halide bond in olefin metathesis (pre)catalysts

Laura FaliveneAlbert PoaterCatherine CazinChristian SlugovcLuigi Cavallo

A1 Journal Article in DALTON TRANSACTIONS

Highly active [Pd(-Cl)Cl(NHC)]2 complexes in the Mizoroki-Heck reaction

Ulrike I TessinXavier BantreilOlivier SongisCatherine Cazin

A1 Journal Article in EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Mixed N heterocyclic carbene/phosphite ruthenium complexes : the effect of a Bulkier NHC

César A. Urbina-BlancoXavier BantreilJulia WappelThibault E SchmidAlexandra MZ SlawinChristian SlugovcCatherine Cazin

A1 Journal Article in ORGANOMETALLICS

Mixed phosphine/N-heterocyclic carbene palladium complexes : synthesis, characterization and catalytic use in aqueous Suzuki-Miyaura reactions

Thibault E SchmidDale C JonesOlivier SongisOlivier DieboltMarc RL FurstAlexandra MZ SlawinCatherine Cazin

A1 Journal Article in DALTON TRANSACTIONS

N-Heterocyclic carbenes

Catherine Cazin

Editorial material

Synergistic ligand effects in ruthenium olefin metathesis

Catherine Cazin

Tandem ammonia borane dehydrogenation/alkene hydrogenation mediated by [Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysts

Caroline E HartmannVaclav JurcikOlivier SongisCatherine Cazin

A1 Journal Article in CHEMICAL COMMUNICATIONS

The isolation of [Pd{OC(O)H}(H)(NHC)(PR3)] (NHC = N-heterocyclic carbene) and its role in alkene and alkyne reductions using formic acid

Julie BroggiVaclav JurcikOlivier SongisAlbert PoaterLuigi CavalloAlexandra MZ SlawinCatherine Cazin

A1 Journal Article in JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

[Pd(NHC)(PR3)] complexes : versatile tools for tandem dehydrogenation-hydrogenation processes

Olivier SongisCatherine Cazin

A1 Journal Article in SYNLETT

2012

An unusual cationic Ru(II) indenylidene complex and its Ru(III) derivative-efficient catalysts for high temperature olefin metathesis reactions

Olivier SongisAlexandra MZ SlawinCatherine Cazin

A1 Journal Article in CHEMICAL COMMUNICATIONS

Catalytic and structural studies of Hoveyda-Grubbs type pre-catalysts bearing modified ether ligands

Stefano GuidoneEnguerrand BlondiauxCezary SamojlowiczLukasz GulajskiMariusz KedziorekMaura MalinskaAleksandra PazioKrzysztof WozniakKarol GrelaAngelino Doppiu et al.

A1 Journal Article in ADVANCED SYNTHESIS & CATALYSIS

Heteroleptic bis(N-heterocyclic carbene)copper(I) complexes : highly efficient systems for the [3+2] cycloaddition of azides and alkynes

Faima LazregAlexandra MZ SlawinCatherine Cazin

A1 Journal Article in ORGANOMETALLICS

Highly active copper-N-heterocyclic carbene catalysts for the synthesis of phenols

Olivier SongisPierre BoulensCallum GM BensonCatherine Cazin

A1 Journal Article in RSC ADVANCES

Mixed NHC/phosphite ligand systems : a new generation of ruthenium olefin metathesis catalysts

Olivier SongisThibault E SchmidYannick BidalStefano GuidoneCatherine Cazin

N-Heterocyclic carbene gold(I) and copper(I) complexes in C-H bond activation

Sylvain GaillardCatherine CazinSteven Nolan

A1 Journal Article in ACCOUNTS OF CHEMICAL RESEARCH

Synergistic effects of mixed ligand systems in catalysis

Olivier SongisXavier BantreilOlivier DieboltCatherine Cazin

Synthesis and reactivity of ruthenium phosphite indenylidene complexes

Xavier BantreilAlbert PoaterCésar A. Urbina-BlancoYannick D BidalLaura FaliveneRebecca AM RandallLuigi CavalloAlexandra MZ SlawinCatherine Cazin

A1 Journal Article in ORGANOMETALLICS

[Pd(IPr*)(cinnamyl)Cl] : an efficient pre-catalyst for the preparation of tetra-ortho-substituted biaryls by Suzuki-Miyaura cross-coupling

Anthony ChartoireMathieu LesieurLaura FaliveneAlexandra MZ SlawinLuigi CavalloCatherine CazinSteven Nolan

A1 Journal Article in CHEMISTRY-A EUROPEAN JOURNAL

[Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysed alcohol oxidation using molecular oxygen

Vaclav JurcikThibault E SchmidQuentin DumontAlexandra MZ SlawinCatherine Cazin

A1 Journal Article in DALTON TRANSACTIONS

2011

Decarboxylation of aromatic carboxylic acids by gold(I)-N-heterocyclic carbene (NHC) complexes

Stephanie DupuyFaima LazregAlexandra MZ SlawinCatherine CazinSteven Nolan

A1 Journal Article in CHEMICAL COMMUNICATIONS

Highly active well-defined palladium precatalysts for the efficient amination of aryl chlorides

Anthony ChartoireMathieu LesieurAlexandra MZ SlawinSteven NolanCatherine Cazin

A1 Journal Article in ORGANOMETALLICS

Influence of a very bulky N-heterocyclic carbene in gold-mediated catalysis

Adrian Gomez-SuarezRuben S RamonOlivier SongisAlexandra MZ SlawinCatherine CazinSteven Nolan

A1 Journal Article in ORGANOMETALLICS

N-Heterocyclic carbenes in transition metal catalysis and organocatalysis

Oxygen binding to [Pd(L)(L')] (L= NHC, L' = NHC or PR3, NHC = N-heterocyclic carbene) : synthesis and structure of a paramagnetic trans-[Pd(NHC)2(η1-O2)2] complex

Xiaochen CaiSubhojit MajumdarGeorge C FortmanCatherine CazinAlexandra MZ SlawinCharles LhermitteRajeev PrabhakarMeaghan E GermainTaryn PalluccioSteven Nolan et al.

A1 Journal Article in JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phosphites as ligands in ruthenium-benzylidene catalysts for olefin metathesis

Thibault E SchmidXavier BantreilCecilia A CitadelleAlexandra MZ SlawinCatherine Cazin

A1 Journal Article in CHEMICAL COMMUNICATIONS

2010

Carboxylation of N-H/C-H bonds using N-heterocyclic carbene copper(I) complexes

Ine IF BoogaertsGeorge C FortmanMarc RL FurstCatherine CazinSteven Nolan

A1 Journal Article in ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper N-heterocyclic carbene (NHC) complexes as carbene transfer reagents

Marc RL FurstCatherine Cazin

A1 Journal Article in CHEMICAL COMMUNICATIONS

Mixed N-heterocyclic carbene/phosphite ruthenium complexes : towards a new generation of olefin metathesis catalysts

Xavier BantreilThibault E SchmidRebecca AM RandallAlexandra MZ SlawinCatherine Cazin

A1 Journal Article in CHEMICAL COMMUNICATIONS

Mixed phosphite/N-heterocyclic carbene complexes : synthesis, characterization and catalytic studies

Olivier DieboltVaclav JurcikRosenildo Correa da CostaPierre BraunsteinLuigi CavalloSteven NolanAlexandra MZ SlawinCatherine Cazin

A1 Journal Article in ORGANOMETALLICS

N-Heterocyclic carbene complexes in industrial processes

Oliver BrielCatherine Cazin

Bookchapter in N-Heterocyclic carbenes in transition metal catalysis and organocatalysis

N-Heterocyclic carbene complexes in oxidation reactions

Václav JurčíkCatherine Cazin

Bookchapter in N-Heterocyclic carbenes in transition metal catalysis and organocatalysis

N-Heterocyclic carbenes : an introductory overview

Luigi CavalloCatherine Cazin

Editorial material

Simple and versatile synthesis of copper and silver N-heterocyclic carbene complexes in water or organic solvents

Cecilia A CitadelleErwan Le NouyFabrice BisaroAlexandra MZ SlawinCatherine Cazin

A1 Journal Article in DALTON TRANSACTIONS

2009

A new stable (CNHCCHCNHC)-C-boolean AND-C-boolean AND N-heterocyclic dicarbene ligand : its mono- and dinuclear Ir(I) and Ir(I)-Rh(I) complexes

Matthieu RaynalCatherine CazinChristophe ValleeHelene Olivier-BourbigouPierre Braunstein

A1 Journal Article in DALTON TRANSACTIONS

Activation of hydrogen by palladium(0) : formation of the mononuclear dihydride complex trans-[Pd(H)(2)(IPr)(PCy3)]

Serena FantasiaJonathan D EgbertVaclav JurcikCatherine CazinHeiko JacobsenLuigi CavalloD Michael HeinekeySteven Nolan

A1 Journal Article in ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly active [Pd(µ-Cl)(Cl)(NHC)]2 (NHC = N-heterocyclic carbene) in the cross-coupling of Grignard reagents with aryl chlorides

Caroline E HartmannSteven NolanCatherine Cazin

A1 Journal Article in ORGANOMETALLICS

Highly efficient catalytic hydrodehalogenation of polychlorinated biphenyls (PCBs)

Said AkzinnayFabrice BisaroCatherine Cazin

A1 Journal Article in CHEMICAL COMMUNICATIONS

Hydrogenation of C-C multiple bonds mediated by [Pd(NHC)(PCy3)] (NHC=N-heterocyclic carbene) under mild reaction conditions

Vaclav JurcikSteven NolanCatherine Cazin

A1 Journal Article in CHEMISTRY-A EUROPEAN JOURNAL

Reaction intermediates in the synthesis of new hydrido, N-heterocyclic dicarbene iridium(III) pincer complexes

Matthieu RaynalRoberto PattaciniCatherine CazinChristophe ValleeHelene Olivier-BourbigouPierre Braunstein

A1 Journal Article in ORGANOMETALLICS

Reactions of amines with zwitterionic quinoneimines : synthesis of new anionic and zwitterionic quinonoids

Farba B TambouraCatherine CazinRoberto PattaciniPierre Braunstein

A1 Journal Article in EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Recent advances in the design and use of immobilised N-heterocyclic carbene ligands for transition-metal catalysis

Catherine Cazin

A1 Journal Article in COMPTES RENDUS CHIMIE

Remarkable base effect in the synthesis of mono- and dinuclear iridium(I) NHC complexes

Matthieu RaynalCatherine CazinChristophe ValleeHelene Olivier-BourbigouPierre Braunstein

A1 Journal Article in ORGANOMETALLICS

Structure and reactivity of new iridium complexes with bis(oxazoline)-phosphonito ligands

Riccardo PelosoRoberto PattaciniCatherine CazinPierre Braunstein

A1 Journal Article in INORGANIC CHEMISTRY

2008

An unprecedented, figure-of-eight, dinuclear iridium(I) dicarbene and new iridium(III) 'pincer' complexes

Matthieu RaynalCatherine CazinChristophe ValleeHelene Olivier-BourbigouPierre Braunstein

A1 Journal Article in CHEMICAL COMMUNICATIONS

Palladium catalysts for room temperature activation of aryl chlorides

Catherine CazinOlivier DieboltSteven NolanPierre Braunstein

Room-temperature activation of aryl chlorides in Suzuki-Miyaura coupling using a [Pd(mu-Cl)Cl(NHC)](2) complex (NHC = N-heterocyclic carbene)

Olivier DieboltPierre BraunsteinSteven NolanCatherine Cazin

A1 Journal Article in CHEMICAL COMMUNICATIONS

2007

Mono- and dinuclear cobalt complexes with chelating or bridging bidentate P,N phosphino- and phosphinito-oxazoline ligands : synthesis, structures and catalytic ethylene oligomerisation

Suyun JieMagno AgostinhoAnthony KermagoretCatherine CazinPierre Braunstein

A1 Journal Article in DALTON TRANSACTIONS

2005

Palladium-catalyzed arylation reactions via palladacycles. Intramolecular biaryl bond formation : exemplified by the synthesis of carbazoles

Catherine CazinMichael BethamRobin B Bedford

Bookchapter in Handbook of C-H transformations : applications in organic synthesis, vol. 1

Versatile methods for the synthesis of Si(OR)(3)-functionalised imidazolium salts, potential precursors for heterogeneous NHC catalysts and composite materials

Catherine CazinM VeithP BraunsteinRB Bedford

A1 Journal Article in SYNTHESIS-STUTTGART

2004

Di- and tri-alkylphosphine adducts of S-donor palladacycles as catalysts in the Suzuki coupling of aryl chlorides

RB BedfordCatherine CazinMB HursthouseME LightEJM Scordia

A1 Journal Article in DALTON TRANSACTIONS

The development of palladium catalysts for C-C and C-heteroatom bond forming reactions of aryl chloride substrates

RB BedfordCatherine CazinD Holder

A1 Journal Article in COORDINATION CHEMISTRY REVIEWS

2003

High-activity catalysts for Suzuki coupling and amination reactions with deactivated aryl chloride substrates : importance of the palladium source

RB BedfordCatherine CazinSJ ColesT GelbrichPN HortonMB HursthouseME Light

A1 Journal Article in ORGANOMETALLICS

Phosphine and arsine adducts of N-donor palladacycles as catalysts in the Suzuki coupling of aryl bromides

RB BedfordCatherine CazinSJ ColesT GelbrichMB HursthouseVJM Scordia

A1 Journal Article in DALTON TRANSACTIONS

2002

A novel catalytic one-pot synthesis of carbazoles via consecutive amination and C-H activation

RB BedfordCatherine Cazin

A1 Journal Article in CHEMICAL COMMUNICATIONS

Alkyne insertion reactions of [RuH(κ2-S2CNEt2)(CO)(PPh3)2] : synthesis of alkenyl, alkynyl and enynyl complexes

Robin B BedfordCatherine Cazin

A1 Journal Article in JOURNAL OF ORGANOMETALLIC CHEMISTRY

Highly active catalysts for the Suzuki coupling of aryl chlorides

Robin B BedfordCatherine Cazin

A1 Journal Article in CHEMICAL COMMUNICATIONS

Silica-supported imine palladacycles : recyclable catalysts for the Suzuki reaction?

Robin B BedfordCatherine CazinMichael B HursthouseMark E LightKevin J PikeStephen Wimperis

A1 Journal Article in JOURNAL OF ORGANOMETALLIC CHEMISTRY

Simple mixed tricyclohexylphosphane-triarylphosphite complexes as extremely high-activity catalysts for the Suzuki coupling of aryl chlorides

RB BedfordCatherine CazinSL Hazelwood

A1 Journal Article in ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Simple tricyclohexylphosphine-palladium complexes as efficient catalysts for the Stille coupling of deactivated aryl chlorides

RB BedfordCatherine CazinSL Hazelwood

A1 Journal Article in CHEMICAL COMMUNICATIONS